The c6 straightchain dicarboxylic acid is slightly soluble in water and soluble in alcohol and acetone. The main use for adipic acid is as a component of nylon66. Adipic acid cas no 124049 material safety data sheet. Adipic acid 124049 1035 sodium carbonate 497198 212 if chemical namecas no is proprietary andor weight% is listed as a range, the specific chemical identity andor percentage of composition has been withheld as a trade secret.
The high purity, excellent uniformity, and consistent enduse performance of adipure makes it a valuable intermediate. No chemicals in this material are subject to the reporting requirements. Adipic acid adipc safety data sheet according to the occupational safety and health classification, labelling, and safety data sheet of hazardous chemicals regulation 20 06042017 en english us 27 name product identifier % classification according to the united nations ghs rev. The substance identifiers displayed in the infocard are the best available substance name, ec number, cas number andor the molecular and structural formulas. Ascend ships adipic acid in a variety of package sizes, including rail cars, tank trucks, super sacks and 50pound bags, via our established, efficient global distribution network. First aid measures always seek professional medical attention after first aid measures are provided.
Adipic acid 124049 1 designates that a specific chemical identity andor percentage of composition has been withheld as a trade secret. Safety data sheet according to 29cfr19101200 and ghs rev. Freezing and thawing does not affect product quality. Adipic acid or hexanedioic acid is the organic compound with the formula ch 2 4 cooh 2. Adipic acid material safety data sheet cas no 124049 sds. Tccs adipic acid is a mildly toxic, white, crystalline compound. What is the chemical equation of sodium hydroxide reacting. Identification of the substancemixture and of the companyundertaking 1. Adipic acid 124049 5000 111111 sara 304 extremely hazardous substances reportable quantity this material does not contain any components with a section 304 ehs rq. Adipic acid neopentyl glycoltrimellitic anhydride copolymer 28407730 na adipic acid neopentyl glycoltrimellitic anhydride copolymer ne 1.
Tartaric acid 87 69 4 not listed on the canadian idl ingredient disclosure list 15. Adipic acid 124049 buy and find out price and availability, msds, properties of tcis high quality specialty chemicals. An 84% conversion of adipic acid s carbon content to carbon dioxide was observed after 30 days aerobic incubation in soil biometer flasks at. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. The first number under the column headed rq is the reportable quantity in pounds. Conventionally it was manufactured from petrochemicals but in recent days it can be synthesized from renewable substrates by means of biological methods.
Oct 15, 2008 adipic acid is a dicarboxylic acid, its has 2 functional group of cooh so 1 mole of adipic acid need 2 moles of naoh in the reaction. Adipic acid otherwise rarely occurs in nature, but it is known as manufactured e number food. First aid measures p312 call a poison center or physician if you feel unwell. Kinetic study of esterification of adipic acid with methanol.
Cornell university insignia cornell law school search cornell. It is one of the most important monomers in the polymer industry. Firstaid measures inhalation remove victim to fresh air and keep at rest in a position comfortable for breathing. This means it has a total of 6 carbons, 10 hydrogens and 4 oxygens.
Biological fluids such as blood and urine have been shown to contain a large number of components, some of them volatiles low boiling point apparently present in all individuals, while others such are much more variable. Neutralize the residue with a solution of acetic acid. Adipic acid 1035% 124049 warning eyes irritant cat. Section 3 hazards identification emergency overview blue liquid. Nearly all commercial adipic acid is produced from cyclohexane. Adipic acid in the urine and in the blood is typically exogenous in origin and is a good biomarker of jello consumption.
Adipic acid is also used in baking powders instead of. Adipic acid 40 641 alcanol 39 625 alfalfa leaf meal 15 240 alfalfa meal 17 272 alfalfa meal, fine ground 19 304 alfalfa pellets 42 673 alfalfa seed 46 737 alumina 40 641 alumina powder 18 288 alumina, activated 48 769 alumina, calcined. Dichloroisocyanuric acid, sodium 2893789 salt 45 adipic acid 124049 35 sigmaaldrich offers a number of adipic acid products. Safety adipic acid is not classified as hazardous for transport. Read this document completely, and then answer the prelab questions below. The mechanical action of pellets or dust may cause irritation or cornell injury. H 319 sodium carbonate 212% 497198 warning eyes irritant cat. Their reactions with bases, called neutralizations, are accompanied by the evolution of substantial amounts of heat. India veritas house, 70 mint road, fort, mumbai 400 001. Ascend safety data sheet reference number 00179 product name ascend nylon 6,6 plus additives class 100 page 26 version 1 date. This is a free site organized by national institute of advanced industrial science and technology aist, japan. Adipic acid is not expected to volatilize from dry soil surfaces based on its extrapolated vapor pressure. Adipic acid is a commercially important chemical used during the production of nylon, plastics, lubricants, adhesives, and polyurethane foam.
Maleic acid material safety data sheet cas no 11016. The most important product manufactured from adipic acid is nylon 66 up to 70 % of the production. Adipic acid is also used in baking powders instead of cream of tartar and other foods. Use of the information, documents and data from the echa website is subject to the terms and conditions of this legal notice, and subject to other binding limitations provided for under applicable law, the information, documents and data made available on the echa website may be reproduced, distributed andor used, totally or in part, for noncommercial purposes provided that echa is.
Find msds or sds, a coa, data sheets and more information. Dichloroisocyanuric acid, sodium salt 2893789 45 adipic acid 124049 35 spectral database for organic compounds,sdbs. Maleic acid cas no 110167 material safety data sheet sds msds. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Dziezak, in encyclopedia of food sciences and nutrition second edition, 2003. In this lesson, the main focal point will be on an organic compound known as adipic acid. Our topics of discussion will include the structure, uses, and hazards associated with adipic acid. Adipic acid is on the hazardous substance list because it is cited by dot, nfpa, acgih and epa. Uses polyamide 66 polymers and fibres polyurethanes organic synthesis lubricants plasticizers coatingsadhesivessealants and elastomers paint and resins flexible and semirigid foams pharmaceutical industry perfumery. Carboxylic acids donate hydrogen ions if a base is present to accept them. Almost 90 percent of adipic acid produced is used in the production of nylon 66.
The market is driven by increasing demand for lightweight and durable products in the automotive, construction, and electronics industries. This msds has been prepared according to the hazard criteria of the controlled products regulations cpr and the msds contains all of the information required by the cpr. Find patient medical information for adipic acid on webmd including its uses, side effects and safety, interactions, pictures, warnings and user ratings. Sigmaaldrich offers a number of adipic acid products. Biodegradability screening tests indicate that adipic acid is readily biodegradable. The acgih tlv and osha pel listed above for sodium molybdate is as molybdenum, soluble compounds. This ketonealcohol ka mixture is then converted to adipic acid by oxidation with nitric acid in the second reaction, as shown in figure. Disclaimer the sds samples above are collected from the internet by chemblink and displayed here for the tutorial purpose only.
Adipic acid basf brenntag product information page. Adipic acid is a white crystalline powder with a slight acid taste and a nil to very faint odour. From an industrial perspective, it is the most important dicarboxylic acid. The direct synthesis of adipic acid from cyclohexene and hydrogen peroxide by a continuous microflow process minjing shang eindhoven university of technology, 2016 a catalogue record is available from the eindhoven university of technology library isbn. The global adipic acid market size was valued at usd 5. Adipic acid has also been incorporated into controlledrelease formulation matrix tablets to obtain phindependent release for both weakly basic and weakly acidic drugs. Ascend is the only largescale producer of foodgrade adipic acid in the world. If relevant, see section 9 for dynamic viscosity and relative density of the product. Adipic acid is composed of carbon, hydrogen and oxygen. Adipic acid is a basic chemical but is also used in consumer products. Adipinic acid 1,4butanedicarboxylic acid hexanedioic acid stop discharge if possible.
Ammonium acetate, 631618, acetic acid ammonium, salt. Welcome to spectral database for organic compounds, sdbs. Adipic acid drug information, uses, side effects, chemistry. Esterification of adipic acid with methanol is an equilibrium reaction in which by using excess of methanol the equilibrium shifts towards formation of ester. Individual protection measures, such as personal protective equipment eyeface protection chemical antisplash safety goggles. On a balance, tare a small test tube that has been placed in an empty 50 to 100ml beaker for stabilization. Adipic acid is a straightchain aliphatic dicarboxylic acid, commonly used in the manufacturing of nylon6,6 and plasticizers. Worldwide demand for adipic acid in 1989 was nearly 2 billion megagrams mg 2 billion tons, with growth continuing at a steady rate. Adipic acid safety msds data this product is from a valetime trading source page one of two general cas 1240409 einecs number 204 673 3 synonyms hexanedioic acid, 1,4butanedicarboxylic acid molecular formula hococh 2 4cooh use manufacture of nylon, polyurethane foams and elastomers, preparation of esters for use. Avoid creating a dust cloud in handling, transfer and clean up. Physical and chemical properties molecular formula hoocch24cooh. Adipic acid cas no 124049 material safety data sheet sds msds. Pdf adipic acid production from lignin researchgate.
Invista adipure highpurity adipic acid is a crystalline, white dicarboxylic acid suitable for a wide variety of applications. Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Adipure high purity adipic acid for a wide range of. Adipic acid 124049 1035% ne ne sodium carbonate 497198 212% ne ne the exact percentages have been withheld as a trade secret. Pdf lignin is an alkylaromatic polymer present in plant cell walls for defense, structure, and water transport. H318 adipic acid is not expected to volatilize from dry soil surfaces based on its extrapolated vapor pressure. Adipic acid is present in some plants and is a chemical in tobacco and tobacco smoke. Additionally, due to high boiling range between adipic acid and methanol, usually excess of methanol is preferred. Adipic acid msds material safety data sheet or sds, coa and coq, dossiers, brochures and other available documents. The nylon, which has a proteinlike structure, is further processed into. Material safety data sheet adipic acid pure version.
Cyclohexanone is occasionally found as a volatile component of human urine. Material safety data sheet adipic acid section 1 chemical product and company identification msds name. Immediately flush eyes with excess water for 15 minutes, lifting lower and upper eyelids occasionally. It is also used in the production of polyurethanes, resins, plasticizers, adhesives, lubricants and in food and pharmaceutical industries. The direct synthesis of adipic acid from cyclohexene and. Alcohol to acid ration of 10, 15 and 20 were tested. Adipic acid msds material safety data sheet or sds, coa and coq, dossiers, brochures and. Adipic acid is found in beet juice, but the article of commerce. They react in this way with all bases, both organic for example, the amines and inorganic. H318 adipic acid, created by global safety management, inc. Cyclohexanone is a colorless oily liquid with an odor resembling acetone and peppermint.
Preparation of adipic acid from cyclohexene in this laboratory period the cyclohexene supposedly prepared in the previous experiment is oxidized to adipic acid. This is a quantitative reaction that converts a liquid cyclohexanone into a solid adipic acid. Nitrous oxide n2o is generated as a byproduct during the production of adipic acid and nitric acid. Adipic acid ada cautionary response information common synonyms solid crystals white odorless sinks and mixes slowly with water. Adipic acid cas no 124049 material safety data sheet sdsmsds. Use a shovel to put the material into a convenient waste disposal container. The substance identity section is calculated from substance identification information from all echa databases. Other information this document is intended only as a guide to the approriate precautionary handling of material by a person taimed in chemical h andling. Adipic acid, a white, crystalline powder, is characterized by low hygroscopicity and a lingering, high tartness that complements grapeflavored products and those with delicate flavors. Signal word warning hazard statements h302 harmful if swallowed. Adipic acid is manufactured from cyclohexane in two major reactions. Us state regulations california proposition 65 this product does not contain any substances known to the state of california to cause cancer, developmental andor reproductive harm. Adipic acid material safety data sheet cas no 12404.1670 1365 407 975 1695 584 635 86 348 307 266 1284 256 288 365 825 1385 265 312 722 191 645 899 469 560 1221 527 6 513 565 245 666 1516 764 332 314 210 1212 73 240